• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    The invention relates to a burner (1) for a fuel cell system (100), in particular an SOFC system, wherein the burner (1) is designed and arranged as start burner and / or afterburner, comprising a first operating fluid guide section (2) and a second operating fluid guide section (FIG. 3), the burner (1) comprising two reaction chambers (6, 7) arranged one after the other and each having a chamber inlet (4a, 4b) and a chamber outlet (5a, 5b), wherein a chamber inlet (4b) of a second reaction chamber ( 7) to a chamber outlet (5a) of a first chamber reaction chamber (6) follows, the reaction chambers (6, 7) each having a catalytic material (18). Furthermore, the invention relates to a use of such a burner (1) and a fuel cell system with such a burner (1). Furthermore, the invention relates to a method for operating a fuel cell system with such a burner (1).
    公开号:AT520612A1
    申请号:T50884/2017
    申请日:2017-10-22
    公开日:2019-05-15
    发明作者:Holthaus Lorenzo；Bernd Reiter Bsc；Dipl Ing Michael (Fh) Reissig；Dominic Leipold Bsc；Ing Thomas Krauss Dipl；Ing Sepp Steiner Dipl；Vötter Rene
    申请人:Avl List Gmbh；
    IPC主号:
    专利说明:

    Summary
    The invention relates to a burner (1) for a fuel cell system (100), in particular an SOFC system, the burner (1) being designed and arranged as a starting burner and / or afterburner, comprising a first operating fluid guide section (2) and a second operating fluid guide section ( 3), the burner (1) comprising two reaction chambers (6, 7) arranged one after the other and each having a chamber inlet (4a, 4b) and a chamber outlet (5a, 5b), a chamber inlet (4b) of a second reaction chamber ( 7) a chamber exit (5a) is followed by a first chamber reaction chamber (6), the reaction chambers (6, 7) each having a catalytic material (18).
    The invention further relates to the use of such a burner (1) and a fuel cell system with such a burner (1).
    The invention also relates to a method for operating a fuel cell system with such a burner (1).
    Fig. 3/30
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    Burner for a fuel cell system with two reaction chambers
    The invention relates to a burner for a fuel cell system, in particular an SOFC system, the burner being designed and arranged as a starting burner and / or afterburner, comprising a first operating fluid guide section and a second operating fluid guide section.
    The invention further relates to the use of such a burner.
    Furthermore, the invention relates to a fuel cell system with such a burner.
    In addition, the invention relates to a method for operating a fuel cell system.
    Burners for fuel cell systems are known from the prior art. Particularly in the case of SOFC systems which are operated with liquid fuel such as diesel or ethanol or an ethanol-water mixture, it may be necessary to evaporate and reform the liquid fuel in a first step. Particularly when using water-containing ethanol, it is difficult or impossible to burn the fuel in a flame burner, which is used, for example, in fuel cell systems which are operated with diesel, due to the high water content (about 55%).
    It is also necessary to heat the fuel cell system to an operating temperature during a cold start, for which purpose a so-called start burner is usually provided. In addition, an afterburner is usually also necessary in order to completely burn off exhaust gas from an anode section. Consequently, a start burner and an afterburner are usually provided in known fuel cell systems.
    The start burner is usually understood to mean a start burner for heating an afterburner of the fuel cell system, which in turn is provided for heating a reformer of the fuel cell system. When the fuel cell system is cold started, when the afterburner is still cold and is therefore not suitable for heating a reformer of the fuel cell system, the afterburner can be preheated by the start burner. As soon as the / 30
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    Afterburner is at operating temperature by operating the fuel cell system, the start burner can be deactivated.
    DE 102 37 744 A1, for example, shows a fuel cell system with a starting burner which is installed in a burner housing. In the burner housing, bypass air can flow along the outside of the starting burner before it enters a mixing zone together with the hot gas emerging from the starting burner. In the mixing zone, the bypass air is mixed as homogeneously as possible with the hot gas in order to emerge as a temperature-controlled hot gas stream and to heat the fuel cell system.
    Furthermore, DE 10 2006 048 984 A1 discloses the use of a burner device in a fuel cell system. The burner device can be operated as an afterburner, anode exhaust gas from a fuel cell or a fuel cell stack being able to be fed to a mixture zone via a fuel gas feed line. The burner device can continue to operate as a starting burner during a starting phase of the fuel cell system, in that the combustion mixture supplied to the burner device is burned even in the absence of a supply of anode exhaust gas. However, this publication does not show how, in particular, a fuel cell system operated with a liquid fuel can be efficiently brought up to operating temperature.
    The object of the invention is to increase the efficiency of a burner of the type mentioned at the outset, by means of which it is simultaneously possible to reduce the number of components in a fuel cell system.
    Another aim is to indicate the use of such a burner.
    Another aim is to provide a fuel cell system with such a burner.
    It is also an aim to provide an improved method for operating a fuel cell system.
    This object is achieved according to the invention in that a burner of the type mentioned at the beginning comprises two reaction chambers which are arranged one after the other and each have a chamber entrance and a chamber exit, with a chamber entrance of a second reaction chamber in the direction of flow to a / 30
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    Chamber exit follows a first chamber reaction chamber, the reaction chambers each having a catalytic material.
    An advantage achieved in this way can be seen in particular in the fact that a burner designed in this way is or can be designed and arranged both as a starting burner and as an afterburner. This means that a single component functions simultaneously as a start burner and as an afterburner, depending on an operating state of a fuel cell system in which the burner is arranged. The burner is designed as a two-stage burner, the first reaction chamber forming a first stage and the second reaction chamber forming a second stage. The first operating fluid and / or second operating fluid can be evaporated in the burner according to the invention on the one hand and at least partially reformed and on the other hand also completely burned and heated to a necessary or predefined temperature. A process gas which flows out of the burner has a sufficiently high temperature due to the two-stage design of the burner to heat fuel and air or operating fluids to an operating temperature for a fuel cell stack via one or more heat exchanger elements. Furthermore, fuel cell exhaust gas, which emerges from the anode section and a cathode section from the fuel cell stack, is completely combustible in the burner, a separate afterburner being therefore unnecessary since the burner can be used as a starting burner and afterburner in a single fuel cell system. The burner according to the invention therefore makes it possible to dispense with an element in a fuel cell system, since it combines two elements.
    According to a first aspect of the present invention, a burner for a fuel cell system, in particular for an SOFC system (SOFC stands for “solid oxide fuel cell” or solid oxide fuel cell), is provided. Such a fuel cell system can be operated with liquid fuel, for example.
    The burner is designed in particular to catalytically burn liquid fuel, for which both reaction chambers each comprise a catalytic material. The concept of the burner, in particular, enables the use of a fuel through the pre-evaporation and partial pre-reforming of the fuel
    Ethanol-water mixture as fuel, which is known for its / 30
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    AVL List GmbH high water content is difficult to evaporate and subsequently burn. This makes it possible to use the highly water-containing fuel, which is intended for steam reforming without the need for recirculation on the anode side, also for the starting process. If the burner according to the invention is arranged in a fuel cell system, however, this can easily be operated with a liquid fuel-water mixture, such as with an ethanol-water mixture.
    The first operating fluid guide section is in particular arranged as a component of the first reaction chamber and is designed to supply a first operating fluid to the burner or the first reaction chamber. If the burner works as a starting burner, the second operating fluid guide section is designed to supply air to the burner. If the burner takes on the function of an afterburner, no operating fluid flows in the first operating fluid guide section in one embodiment variant, whereas anode exhaust gas or fuel cell exhaust gas (anode exhaust gas and cathode exhaust gas) flows in the second operating fluid guide section, which is fed to the burner in order to burn it completely. Since cathode exhaust gas is in particular exclusively air, the anode exhaust gas is burned in the burner with the cathode exhaust gas. If the temperature of the burner is too high as an afterburner, it may be advantageous to supply the burner with additional air.
    In a further embodiment variant, it can also be advantageous if the first operating fluid is guided in the first operating fluid guide section when the burner is operating as an afterburner. The reactions below then take place analogously to operation as a start burner, except that the second operating fluid is not air but anode exhaust gas or fuel cell exhaust gas. The first operating fluid is preferably a liquid fuel-water mixture, in particular an ethanol-water mixture.
    The two reaction chambers of the burner in particular adjoin one another directly, so that the chamber outlet of a first reaction chamber connects to the chamber inlet of the second reaction chamber. A mixture of air and a fuel-water mixture or fuel cell exhaust gas flows through the two reaction chambers in succession; the second reaction chamber is therefore arranged downstream of the first reaction chamber. They are then arranged one after the other in the direction of flow.
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    It is expedient if the reaction chambers are each designed to be rotationally symmetrical, at least in sections, each comprising at least two, in particular cylindrical, layers. The reaction chambers are particularly preferably hollow-cylindrical at least in sections. The cylindrical layers are in particular inserted coaxially into one another or arranged in relation to one another. As a result, chambers can form between the cylindrical layers.
    It is advantageous if a first reaction chamber comprises an electrical heating device. As a result, the burner can be electrically preheated when the burner is started. In particular, the electrical heating means is designed to heat the first operating fluid, particularly preferably the heating means is designed exclusively to heat, evaporate and / or reform the first operating fluid during a warm-up phase of the burner functioning as a starting burner. The first operating fluid, which is present as a fuel or as a fuel-water mixture, is consequently not only preheatable, but also vaporizable and can be pre-reformed to a certain predetermined degree. As a result, the burner can be operated particularly effectively when used as a starting burner. In the case of a heating operation, the electrical heating device can be in operation for a period of approximately 2 minutes to 10 minutes, for example. When the burner is used as an afterburner, the electrical heating medium is generally not used. Electrical support for evaporation and reforming can in principle be carried out in an external component, but integration of this function is desirable for reasons of space.
    It is advantageous if a first, radially outermost cylindrical layer of the first reaction chamber is designed as an evaporation sheath, the electrical heating device being arranged between the evaporation sheath and a second cylindrical layer and in particular at least partially spiraling around a second cylindrical layer. This means that the heating medium is arranged in a particularly space-saving manner in the starting burner. An evaporation chamber is advantageously formed radially between the evaporation envelope and the second cylindrical layer. The evaporation envelope radially surrounds the evaporation chamber. The reactions taking place in the evaporation chamber (vaporization and pre-reforming of the first operating fluid) can be understood as a preliminary stage or a sub-stage of the first stage of the burner. The / 30
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    Heating means leads in particular over an almost entire axial length of the first reaction chamber in a spiral around the second cylindrical layer; it forms a heating coil. Within the scope of the invention, all cylindrical layers are to be understood as hollow-cylindrical layers unless clearly described otherwise.
    It is expedient if the first operating fluid guide section extends at least partially in a spiral around the second cylindrical layer. In particular, the spiral-shaped first operating fluid guide section thus formed runs between the heating coil formed in such a way that the first operating fluid flows around the heating coil. As a result, the first operating fluid carried in the first operating fluid guide section is particularly efficient and can be heated in a short period of time. The first operating fluid is introduced at one point into the spiral-shaped first operating fluid guide section, which is arranged closer to the chamber outlet than to the chamber inlet of the first reaction chamber. The spiral-shaped first operating fluid guide section ends approximately in the region of the chamber entrance of the first reaction chamber, where, when the burner is operating as a starter burner, the first operating fluid is mixed with air and conducted into the first reaction chamber within a radially innermost cylindrical layer. A distance of the first operating fluid to be covered in the spiral-shaped first operating fluid guide section is consequently long enough to ensure that the first operating fluid is not only heated but also almost or completely evaporated and at least partially reformed or pre-reformed before it is mixed with air. The electric heating device and the first operating fluid guide section each run at least partially within the evaporation chamber. The heating device is designed in a spiral shape and the first operating fluid flows around it. In order to specify a flow direction for the operating fluid, baffle plates are arranged in the evaporation chamber, so that the first operating fluid flows in a spiral in the direction of the chamber entrance of the first chamber. The second cylindrical chamber can advantageously be provided with ribs on the walls in order to increase the heat transfer to the first cylindrical chamber as soon as the electrical support is switched off.
    It is also expedient if the first operating fluid guide section has at least two
    Includes sections, a first section for feeding a first
    Part of the first operating fluid to the chamber entrance of a first
    Reaction chamber and a second section for feeding a second part / 30
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    AVL List GmbH of the first operating fluid to the chamber entrance of the first reaction chamber is formed. The first section is arranged spirally around the second cylindrical layer as described above and advantageously guides about 70% of the first operating fluid as described to the chamber entrance of the first reaction chamber. The second section is substantially shorter than the first section, but also runs in a spiral around the second cylindrical layer. About 30% of the first operating fluid is passed through the second section, this part of the first operating fluid being directed in the direction of the chamber outlet of the first reaction chamber. This takes place in particular when the burner is operated as a starting burner, but it can also be provided that when operating as an afterburner the first operating fluid can be supplied to the first chamber as described at least through the first or second section.
    It is advantageous if the second operating fluid guide section is designed to supply a second operating fluid to the chamber entrance of the first reaction chamber, a shield for deflecting the second operating fluid being arranged at the chamber entrance of the first reaction chamber. In the area of the chamber entrance of the first reaction chamber, the gaseous, in particular partially reformed, first operating fluid is mixed with the second operating fluid. When operating as a starting burner, the second operating fluid is air, in particular ambient air, which can be supplied either directly via an external source or preferably via a cathode circuit of a fuel cell system. This burns the second operating fluid designed as a fuel / water mixture during operation as a start burner. In order to achieve a particularly efficient mixing of the second operating fluid with the fuel-water mixture, the shield is provided, which is in particular circular and full-area and extends radially to approximately the second cylindrical layer. The inflowing second operating fluid hits the shield and is guided by it in the direction of the inflowing fuel-water mixture. This arrangement largely prevents poor mixing of the fuel / water mixture with the second operating fluid. The radially innermost cylindrical layer is advantageously designed as a perforated hollow cylinder. The hollow cylinder is formed in particular from a metal or a metal alloy and forms a radially innermost element of the first / 30th
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    Reaction chamber. The second operating fluid or a mixture of the first and second operating fluids is conducted via guide elements into an interior of the perforated wooden cylinder. Due to the radially formed perforations in the hollow cylinder, the second operating fluid or a mixture of the first and second operating fluids is directed radially outward in the direction of the second cylindrical layer.
    It is advantageous if the catalytic material of the at least first reaction chamber is designed as a catalytically coated fabric, which is arranged in particular in a ring around a radially innermost cylindrical layer. Basically, the catalytic material formed as a coated fabric can be shaped as desired. In the context of the invention, this is preferably arranged in a ring on a wall of the radially innermost cylindrical layer. The fabric has a radially greater thickness than the innermost radial layer, the second cylindrical layer and the evaporation envelope. A radially inner end advantageously forms a catalyst inlet, whereas a radially outer end of the catalytic layer forms a catalyst outlet. The fabric is preferably formed with a plurality of radial perforations or channels so that it can be flowed through radially from the inside out, the first and / or second operating fluid being catalytically burned. In comparison to burners for fuel cell systems known from the prior art, this has the advantage that a pressure loss of the mixture through the tissue forming a catalyst is significantly reduced.
    In order to use the heat generated during the catalytic combustion, heat-conducting elements are advantageously arranged between the coated fabric and the second cylindrical layer. Heat can be transferred radially outward from the catalytic combustion in the tissue to the spiral operating fluid guide section via the heat-conducting elements, which can be designed, for example, as ribs. This enables the electrical heating device to be switched off after a short period of time, in particular after a catalytic reaction has started. That for the further evaporation of the first operating fluid in the first operating control section is thus made available by the catalytic combustion.
    The first operating fluid is in particular completely combustible in the first reaction chamber. The resulting waste heat is the first / 30
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    Operating fluid in the first operating fluid supply line can be evaporated and partially reformed before it is introduced into the chamber entrance of the first reaction chamber. As a result, operation of the electric heating device can be dispensed with as soon as waste heat is generated. In addition, the resulting combustion gas is only heated up to a temperature of around 600 ° C; the remaining heat is used to evaporate the first operating fluid. On the one hand, this means that a permissible maximum temperature of common catalytic materials of about 1000 ° C. is not exceeded and, on the other hand, individual hot spots in the first reaction chamber are avoided, as a result of which homogeneous mixing can be achieved.
    It is advantageous if the second reaction chamber comprises a perforated hollow cylinder and a catalytically coated fabric, the fabric at least partially enclosing the perforated hollow cylinder in the circumferential direction. In contrast to the first reaction chamber, a radially inner end advantageously forms a catalyst outlet, whereas a radially outer end forms a catalyst inlet. The fabric is preferably formed with a plurality of radial perforations or channels, so that it can be flowed through from radially outside to inside. In particular, the second reaction chamber is designed to increase the temperature of the process gas to a maximum temperature in a function of the burner as a starting burner, this being limited by catalytic material and being around 950 ° C. in the case of currently customary materials. Since part of the first operating fluid is only supplied to the axial end of the first reaction chamber, this is catalytically burned in the second reaction chamber, as a result of which the temperature of the process gas leaving the burner increases significantly. This is also made possible by the fact that no waste heat from the combustion is used for other purposes in the second reaction chamber. A maximum temperature of the process gas can thus be achieved by the two-stage burner without damaging the catalytic material of the burner. A service life of the burner is consequently increased, since decomposition of the catalytic material is reduced, in particular almost avoided. In the second reaction chamber, a distribution between the first operating fluid and the gaseous mixture is more homogeneous, which is why a temperature distribution in the second reaction chamber is also homogeneous. Consequently, a maximum temperature of the process gas to be achieved is better / 30
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    AVL List GmbH can be approximated. The operation of the second reaction chamber is essentially the same when operating as a starting burner and when operating as an afterburner.
    A burner according to the invention is advantageously used as a starting burner and afterburner in a fuel cell system which is operated with liquid fuel.
    According to a further aspect of the present invention, a fuel cell system with a burner as detailed above is provided. The fuel cell system furthermore has a fuel cell stack with an anode section and a cathode section as well as an evaporator and a reformer, the burner being arranged and designed for heating the reformer, the evaporator and a heat exchanger which is responsible for heating air to be supplied from the cathode section . A fuel cell system according to the invention thus has the same advantages as have been described in detail with reference to the burner according to the invention. The fuel cell system is preferably an SOFC system. The reformer is preferably designed to reform a fuel mixture, for example ethanol and water, into another fuel mixture, in this case hydrogen and carbon dioxide. The reformed hydrogen can be used in a fuel cell stack to generate electricity. The burner is designed to heat the reformer by means of fuel cell exhaust gas from the fuel cell stack. In an advantageous development of the present invention, it is possible for a further heat exchanger to be provided, process gas which emerges from the burner flowing over a warm side of the heat exchanger and air flowing over a cold side of the heat exchanger to a cathode section of the fuel cell stack. warmed up. Furthermore, it can be advantageous if an additional heat exchanger is arranged downstream of the fuel cell stack and upstream of the reformer or the further heat exchanger. This is designed to adapt the inlet temperatures of the operating fluids (fuel-water mixture and air). The aim is to keep temperature differences between the two operating fluids as low as possible so that thermal stresses in the fuel cell stack are largely / 30
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    AVL List GmbH can be avoided. The fuel cell system according to the invention is used in particular in a motor vehicle.
    The further goal is achieved if a method of the type mentioned at the beginning comprises the following steps:
    - putting an electrical heating device into operation and introducing a first operating fluid into a first operating fluid guide section in order to at least evaporate the first operating fluid;
    Introducing a second operating fluid through a second operating fluid guide section to a chamber entrance of a first reaction chamber;
    Directing the first operating fluid via the first operating fluid guide section to the chamber entrance of the first reaction chamber;
    - Mixing the first operating fluid with the second operating fluid at the chamber entrance of the first reaction chamber, the second operating fluid being deflected via a shield;
    - Catalytic combustion of the operating fluid mixture;
    - Switch off the electrical heating device.
    An advantage achieved in this way can be seen in particular in the fact that a fuel cell system can be warmed up efficiently and in a short time by the steps of the method according to the invention, the burner itself also being warmed up efficiently and quickly. When the burner is operated as a start burner, the second operating fluid is air, whereas the first operating fluid is a fuel or a fuel-water mixture. As soon as the operating fluid mixture is burned, the electric heating device is switched off, since the combustion generates heat, by means of which the first operating fluid is heated and evaporated before being introduced into the burner. In particular, the first operating fluid in the first operating fluid guide section is not only completely evaporated, but is also at least partially pre-reformed. The electrical heating device can initially be activated for heating or preheating the first operating fluid until a defined operating temperature is reached in the burner or in the catalytic part of the burner. As soon as the defined operating temperature has been reached, the electrical heating device can be deactivated. The remaining procedural steps are then repeated. The others with the burner functioning as / 30
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    The advantages and functions associated with starting burners are the same as those described in detail above with reference to the burner according to the invention and the fuel cell system according to the invention.
    It is further advantageous if a second part of the first operating fluid is fed to a chamber outlet of the first reaction chamber, the second part of the first operating fluid and the gaseous operating fluid mixture being passed into the second reaction chamber and being catalytically burned in the second reaction chamber. As a result, a process gas emerging from the burner is raised to a desired and defined process temperature without damaging the catalytic parts of the burner.
    It is advantageous if the resulting process gas downstream of the burner is used at least to heat a reformer and an evaporator, the first operating fluid being supplied to the reformer and the evaporator. The first (liquid) operating fluid is consequently evaporated in the evaporator by the process gas heated in the burner, the first operating fluid being supplied to the evaporator via an anode feed line. In the reformer, which is arranged downstream of the evaporator, the now gaseous first operating fluid is reformed by the hot process gas. The process gas emerging from the burner has a temperature of approximately 950 ° C. and can additionally or alternatively also be used to heat at least one heat exchanger, through which the air (second operating fluid), which is fed to the cathode section via a cathode supply line, is heated becomes. In principle, it is favorable if the first and second operating fluids are introduced into the fuel cell stack at approximately the same temperature, which is why they are advantageously passed downstream of the heat exchanger through an additional heat exchanger which adjusts the temperatures of the two operating fluids.
    In terms of the method, it is expedient for the fuel to be fed to the anode section downstream of the reformer, with Andean exhaust gas being mixed with cathode exhaust gas downstream of the fuel cell stack and being fed to the burner via the second operating fluid guide section. This process step uses the burner as an afterburner. As a result, the burner is used both as a start burner and as an afterburner. A method according to the invention thus also has the same advantages as it / 30
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    AVL List GmbH have been described in detail above with reference to the start burner according to the invention and the fuel cell system according to the invention.
    It is advantageous if the anode exhaust gas is burned with the cathode exhaust gas in two stages in the burner, the supply of the first operating fluid via the first operating fluid guide section preferably being stopped. Since cathode exhaust gas (air) is already added to the anode exhaust gas, it is advantageously no longer necessary to supply air. Although it may be advantageous for the burner to function as an afterburner if no first operating fluid is supplied to the burner, it may be advantageous if fuel or a fuel / water mixture is supplied to the burner at least temporarily via the first operating fluid guide section.
    After the burner has been started up as a starting burner, this hot exhaust gas conveys a heat exchanger to an anode section and a cathode section of a fuel cell system. The fuel cell system is heated by conveying ambient air over a cold side of a heat exchanger in the cathode circuit to the cathode section. As soon as an operating temperature is reached in the fuel cell system, an anode current can be activated. At the same time, a fuel supply to the start burner is deactivated and the component (burner) goes into passive operation of the afterburner, which treats the fuel cell exhaust gas by total oxidation. This is possible because outlet flows from the stack are directed directly into the burner's chamber entrance.
    Further advantages, features and effects result from the exemplary embodiments shown below. In the drawings, to which reference is made, show:
    1 shows a burner according to the invention,
    2 shows another burner according to the invention;
    3 shows a section through a burner according to the invention;
    4 shows a block diagram for illustrating a fuel cell system according to an embodiment of the invention.
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    1 and 2 show a burner 1 according to the invention for a fuel cell system 100. This comprises two reaction chambers 6, 7, which are arranged one behind the other in the direction of flow. Each reaction chamber 6, 7 has a chamber entrance 4a, 4b and a chamber exit 5a, 5b. The burner 1 further has a first operating fluid guiding section 2 and a second operating guiding section 3, the first operating fluid guiding section 2 being designed for guiding a first operating fluid and the second operating fluid guiding section 3 being designed for guiding a second operating fluid. In the context of the invention, an ethanol-water mixture is preferably used as the first operating fluid and air is used as the second operating fluid. The first operating fluid guide section 2 comprises a first section 2a and a second section 2b.
    As can be seen from FIGS. 1 and 2, both a first reaction chamber 6 and a second reaction chamber 7 of the burner 1 are constructed as hollow cylinders; these each have a plurality of cylindrical layers 8, 9, 10, 14, 15, 18. A radially innermost layer 10, 14 is designed as a metallic, perforated hollow cylinder. Both reaction chambers 6, 7 are closed radially outward with a radially outermost cylindrical layer 8, 16. The radially outermost cylindrical layer 8 of the first reaction chamber 6 is designed as an evaporation envelope, between which and a second cylindrical layer 9 an evaporation chamber is formed. The first operating fluid is vaporized and pre-reformed in the evaporation chamber.
    3 shows a section through the burner 1 according to the invention. The first reaction chamber 6 is constructed radially from the outside in as follows: The radially outermost cylindrical layer 8, which is designed as an evaporation sleeve, includes a spiral electrical heating device 11, which extends spirally around a second cylindrical layer 9 and as can be seen in FIGS. 1 and 2 enters the evaporation sleeve in the area of the chamber entrance 4a of the first chamber 6. Likewise and alternately with the electric heating device 11, the first operating fluid guide section 2 extends around the second cylindrical layer 9. As a result, a first operating fluid can be heated and evaporated when a fuel cell system 100 is cold started. Radially inside the second cylindrical layer 9 there are heat-conducting elements 13 which connect to a catalytic layer 18. The radially innermost layer 8, which is designed as a perforated hollow cylinder, is arranged radially inside the catalytic layer 18. The second / 30th
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    Reaction chamber 7 comprises fewer sub-elements than the first reaction chamber 6 and is constructed radially from the outside in as follows: An outermost cylindrical layer 16 closes off the second reaction chamber 7 from the outside. A catalytic layer 18 is again provided within this. This is generally of the same design as the catalytic layer 18 of the first reaction chamber 6. The catalytic layers 18 of the first and second reaction chambers 6, 7 are particularly preferably designed as a catalytically coated fabric 15; According to FIG. 3, the catalytic layer 18 thus corresponds to the tissue 15. The radially inner layer 14, which is formed as a metallic, perforated hollow cylinder, adjoins this on the radial inside. The fabric 15 runs radially around the perforated hollow cylinder, both the hollow cylinder and the fabric 15 being formed with radial perforations.
    Both reaction chambers 6, 7 each have a chamber entrance 4a, 4b and a chamber exit 5a, 5b. A shield 12 for deflecting the second operating fluid is arranged in the area of the chamber entrance 4a of the first reaction chamber 6. In order to guide the second operating fluid or a mixture of the first and second operating fluid into an inner region of the innermost layer 8, guide elements 17 are further provided. Heated process gas flows out of the burner 1 via the chamber outlet 5b of the second reaction chamber 7.
    4 shows a block diagram of a fuel cell system 100 with the burner
    1. The fuel cell system 1 further comprises an evaporator 140, a reformer 150, two heat exchangers 160, 170 and a fuel cell stack 110 with an anode section 120 and a cathode section 130. The fuel cell system 100 is operated with a liquid fuel-water mixture which is operated via a Anode supply line 20 via the evaporator 140 (there the fuel-water mixture is gaseous), the reformer 150 (there the gaseous fuel-water mixture is reformed) and the further heat exchanger 170 are fed to the anode section. Air is supplied to the cathode section 130 via a heat exchanger 160 and the further heat exchanger 170 via a cathode supply line. These steps are carried out when the fuel cell system 100 is in operation, that is to say after a heating-up operation.
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    The burner 1 according to the invention is used as a starting burner for heating the fuel cell system 100: the electric heating device 11 is put into operation and the first operating fluid is introduced into the first operating fluid guide section 2. There it is heated with the heating device 11, evaporated and partially reformed. Shortly thereafter, air is introduced or passed through a second operating fluid guide section 3 and the fuel-water mixture to the chamber entrance 4a of the first reaction chamber 6 and mixed there. The mixture is directed radially outward in the direction of the catalytic layer 18 and is catalytically burned there. Since heat is given off by the combustion, the electric heating device 11 can now be switched off. At the chamber exit 5a of the first reaction chamber 6, a second part of the fuel-water mixture is fed and this is passed into the second reaction chamber 7 with the already gaseous fuel-water-air mixture. Again, catalytic combustion takes place there. A process gas emerging from the second reaction chamber now has a temperature of approximately 950 ° C. As shown in FIG. 4, this process gas heats the reformer 150, the heat exchanger 160 and the evaporator 140 in the flow direction. The inflowing air to the heat exchanger 160 in turn heats up the fuel cell stack 110. As soon as all elements have a predefined operating temperature, the function of the burner 1 as a starting burner is no longer required, that is to say it is preferred that no first operating fluid is supplied via the first operating fluid guide section 2.
    When operating the fuel cell system 100, the burner 1 is used as an afterburner. The anode exhaust gas is mixed with the cathode exhaust gas downstream of the fuel cell stack 110. This stack exhaust gas is fed to the burner 1 via the second operating fluid guide section 3 and is burned there in particular in two stages.
    According to FIG. 4, a valve 180 is further provided in the fuel cell system 100. This is designed and arranged to cool the burner 1 with air if necessary. This may be necessary, for example, when a battery which is supplied with electrical energy provided by the fuel cell system 100 is full and cannot be supplied further. Then the fuel cell stack 110 switches off automatically. However, the superfluous fuel in the fuel cell system 100 is further promoted and not / 30
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    Fuel cell stack 110 used, but the fuel goes directly through the fuel cell stack 110 into the burner 1. There is a risk that the maximum temperatures permitted in the burner 1 will be exceeded, which is why the burner 1 is cooled with air from the cathode supply line 30 by opening the valve 180 becomes.
    The burner 1 according to the invention can be used in a fuel cell system 100 both as a starting burner and as an afterburner. When the fuel cell system 100 is heated, it is used as a starting burner and when the fuel cell system 100 is operating as an afterburner.
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    PP31740AT
    AVL List GmbH
    权利要求:
    Claims (18)
    [1]
    Claims
    1. Burner (1) for a fuel cell system (100), in particular a SOFC system, the burner (1) being designed and arranged as a starting burner and / or afterburner, comprising a first operating fluid guide section (2) and a second operating fluid guide section (3), thereby characterized in that the burner (1) comprises two reaction chambers (6, 7) arranged one after the other and each having a chamber inlet (4a, 4b) and a chamber outlet (5a, 5b), a chamber inlet (4b) of a second reaction chamber (7 ) follows a chamber outlet (5a) of a first chamber reaction chamber (6), the reaction chambers (6, 7) each having a catalytic material (18).
    [2]
    2. Burner (1) according to claim 1, characterized in that the reaction chambers (6, 7) are each rotationally symmetrical at least in sections, each of which comprises at least two in particular cylindrical layers (8, 9, 10, 14, 15, 18) .
    [3]
    3. Burner (1) according to claim 1 or 2, characterized in that the first reaction chamber (6) has an electrical heating device (11).
    [4]
    4. Burner (1) according to claim 3, characterized in that a first, radially outermost cylindrical layer (8) of the first reaction chamber (6) is designed as an evaporation envelope, wherein the electrical heating device (11) between the evaporation envelope and a second cylindrical layer (9) extending and in particular at least partially arranged spirally around a second cylindrical layer (9).
    [5]
    5. Burner (1) according to one of claims 1 to 4, characterized in that the first operating fluid guide section (2) extends at least partially in a spiral around the second cylindrical layer (9).
    [6]
    6. Burner (1) according to one of claims 1 to 5, characterized in that the first operating fluid guide section (2) comprises at least two sections (2a, 2b), a first section (2a) for supplying a first part of a first operating fluid for Chamber entrance (4a) of the first reaction chamber (6) and a second section (2b) for feeding a second part of the first
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    AVL List GmbH
    Operating fluid to the chamber outlet (5a) of the first reaction chamber (6) is formed.
    [7]
    7. Burner (1) according to one of claims 1 to 6, characterized in that the second operating fluid guide section (3) is designed for supplying a second operating fluid to the chamber entrance (4a) of the first reaction chamber, the chamber entrance (4a) of the first reaction chamber ( 6) a shield (12) for deflecting the second operating fluid is arranged.
    [8]
    8. burner (1) according to any one of claims 1 to 7, characterized in that the radially innermost cylindrical layer (10, 14) of the reaction chambers (6, 7) is each formed as a perforated hollow cylinder.
    [9]
    9. burner (1) according to any one of claims 1 to 8, characterized in that the catalytic material (18) of the at least first reaction chamber (6) is designed as a catalytically coated fabric (15), this in particular annularly around the radially innermost cylindrical layer (10) is arranged.
    [10]
    10. Burner (1) according to claim 9, characterized in that heat-conducting elements (13) are arranged between the coated fabric (15) and the second cylindrical layer (9).
    [11]
    11. Burner (1) according to one of claims 1 to 10, characterized in that the second reaction chamber (7) comprises a perforated hollow cylinder (14) and a catalytically coated fabric (15), the fabric (15) the perforated hollow cylinder ( 14) at least partially encloses in the circumferential direction.
    [12]
    12. Use of a burner (1) according to one of claims 1 to 11 as a starting burner and afterburner in a fuel cell system (100) which is operated with liquid fuel.
    [13]
    13. Fuel cell system (100), in particular SOFC system with a burner (1) according to one of claims 1 to 11, characterized in that the fuel cell system (100) further comprises a fuel cell stack (110) with an anode section (120) and a cathode section ( 130) and an evaporator (140) and a reformer (150).
    [14]
    14. A method for operating a fuel cell system (100) with a burner (1) according to one of claims 1 to 11, in particular one
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    PP31740AT
    AVL List GmbH
    The fuel cell system (100) according to claim 13, wherein the method comprises the following steps:
    - Commissioning an electrical heating device (11) and introducing a first operating fluid into a first operating fluid guide section (2) in order to at least evaporate the first operating fluid;
    - Introducing a second operating fluid through a second
    Operating fluid guide section (3) to a chamber entrance (4a) of a first reaction chamber (6);
    - guiding the first operating fluid via the first operating fluid guide section (2) to the chamber entrance (4a) of the first reaction chamber (6);
    - Mixing the first operating fluid with the second operating fluid at the chamber entrance (4a) of the first reaction chamber (6), the second operating fluid being deflected via a shield (12);
    - Catalytic combustion of the operating fluid mixture;
    - Switch off the electric heating device (11).
    [15]
    15. The method according to claim 15, characterized in that a second part of the first operating fluid is fed to a chamber outlet (5a) of the first reaction chamber (6), the second part of the first operating fluid and the gaseous operating fluid mixture in the second reaction chamber ( 7) passed and burned catalytically in the second reaction chamber (7).
    [16]
    16. The method according to claim 15, characterized in that the resulting process gas downstream of the burner (1) is used to heat a reformer and an evaporator, the reformer and the evaporator being supplied with the first operating fluid.
    [17]
    17. The method according to claim 16, characterized in that the fuel is fed downstream of the reformer (150) to the anode section (120), wherein andean exhaust gas is mixed with cathode exhaust gas downstream of the fuel cell stack (110) and the burner (1) via the second operating fluid guide section (3 ) is supplied.
    [18]
    18. The method according to claim 17, characterized in that the anode exhaust gas is burned with the cathode exhaust gas in two stages in the burner (1),
    21/30
    PP31740AT
    AVL List GmbH whereby the first operating fluid is supplied via the first
    Operating fluid guide section (2) is preferably stopped
    22/30
    PP31740AT
    AVL List GmbH
    1/3
    23/30
    PP31740AT
    AVL List GmbH
    2/3
    B
    B
    B
    Γ
    I.
    Β φ φ φ ί®ΦΦ φ φ ι (Φ φ φ φ (Φ φ Φ Φ «φφφ φ ιφφ φ φ • φφφ φ ΚΦΦΦ φ ®Φ0 φ φ : * φ φ φ φ
    1 I ί J
    ΙΙΟΦΦ ♦ ΦΦΦ Φ ι »ΦΦ Φ Φ ΚΟΦ Φ IW® ΙΦΟ Φ Φ ΙΦφ φ φ ηηφ ¢ 1 r <r · φφ <· i
    B φ Φ ΦΦΙ
    B Φ Φ ΦΦΙ
    B Φ Φ ΦΦΙ
    Fig. 3
    24/30
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    AVL List GmbH
    3/3
    25/30 Austrian
    Patent office
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    同族专利:
    公开号 | 公开日
    AT520612B1|2020-04-15|
    BR112020007597A2|2020-11-03|
    CN111226337A|2020-06-02|
    WO2019075502A1|2019-04-25|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    EP1465274A2|2003-04-03|2004-10-06|J. Eberspächer GmbH Co. KG|Fuel cell system and a burner arrangement for a fuel cell system|
    WO2008091801A2|2007-01-22|2008-07-31|Rolls-Royce Fuel Cell Systems Inc.|Multistage combustor and method for starting a fuel cell system|
    EP2336083A1|2009-12-17|2011-06-22|Topsøe Fuel Cell A/S|Gas generator and processes for the conversion of a fuel into an oxygen-depleted gas and/or hydrogen-enriched gas|
    EP2407224A1|2010-07-16|2012-01-18|Samsung SDI Co., Ltd.|Catalytic combustor for a reformer for a fuel cell|
    US8309270B2|2007-08-03|2012-11-13|Cp Sofc Ip, Llc|Solid oxide fuel cell systems with improved gas channeling and heat exchange|
    AT508488A1|2009-07-13|2011-01-15|Vaillant Group Austria Gmbh|AFTERBREAKER FOR NATURAL GAS-BASED FUEL CELL HEATERS|WO2019178627A1|2018-03-19|2019-09-26|Avl List Gmbh|Fuel cell system and method for heating up a fuel cell system|
    AT522939B1|2019-09-09|2021-09-15|Avl List Gmbh|Burner for a fuel cell system|
    AT523316B1|2019-12-18|2021-11-15|Avl List Gmbh|Fuel cell system and method for operating a fuel cell system|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    ATA50884/2017A|AT520612B1|2017-10-22|2017-10-22|Burner for a fuel cell system with two reaction chambers|ATA50884/2017A| AT520612B1|2017-10-22|2017-10-22|Burner for a fuel cell system with two reaction chambers|
    CN201880067652.3A| CN111226337A|2017-10-22|2018-10-22|Burner for fuel cell system having two reaction chambers|
    BR112020007597-3A| BR112020007597A2|2017-10-22|2018-10-22|fuel cell system, in particular, sofc system with a burner, method of operation of this system, burner for this system, use of this burner|
    PCT/AT2018/060251| WO2019075502A1|2017-10-22|2018-10-22|Burner for a fuel cell system with two reaction chambers|
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